PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)

            \(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

            \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)

a) Ta có: \(n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{6,2}{62}=0,2\left(mol\right)\)

\(\Rightarrow C\%_{NaOH}=\dfrac{0,2\cdot40}{193,8+6,2}\cdot100\%=4\%\)

b) Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=0,2\left(mol\right)\\n_{CuSO_4}=\dfrac{200\cdot16\%}{160}=0,2\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,2}{1}\) \(\Rightarrow\) CuSO₄ còn dư, NaOH p/ứ hết

\(\Rightarrow n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{NaOH}=n_{CuO}=0,1\left(mol\right)\)

\(\Rightarrow m_{CuO}=0,1\cdot80=8\left(g\right)\)

c) PTHH: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)

Theo PTHH: \(n_{HCl}=2n_{CuO}=0,2\left(mol\right)\) \(\Rightarrow V_{ddHCl}=\dfrac{0,2}{2}=0,1\left(l\right)=100\left(ml\right)\)

Câu 1:

PTHH: \(Na_2O+H_2O\rightarrow2NaOH\) 

            \(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

            \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)

a) Ta có: \(n_{NaOH}=2n_{Na_2O}=2\cdot\dfrac{12,4}{62}=0,4\left(mol\right)\)

\(\Rightarrow C\%_{NaOH}=\dfrac{0,4\cdot40}{12,4+193,8}\cdot100\%\approx7,76\%\)

b) Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=0,4\left(mol\right)\\n_{CuSO_4}=\dfrac{100\cdot16\%}{160}=0,1\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,4}{2}>\dfrac{0,1}{1}\) \(\Rightarrow\) NaOH còn dư, CuSO₄ p/ứ hết

\(\Rightarrow n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuSO_4}=0,1\left(mol\right)\)

\(\Rightarrow m_{CuO}=0,1\cdot80=8\left(g\right)\)

Bài 2 : 

a)

$Cu + 2H_2SO_{4_{đặc}} \to CuSO_4 + SO_2 + 2H_2O$
$n_{Cu} = n_{SO_2} = \dfrac{2,24}{22,4} = 0,1(mol)$
$\%m_{Cu} = \dfrac{0,1.64}{15}.100\% = 42,67\%$
$\%m_{CuO} = 100\% -42,67\% = 57,33\%$

b)

$NaOH + SO_2 \to NaHSO_3$
$n_{NaOH} = n_{SO_2} = 0,1(mol)$

$\Rightarrow V_{dd\ NaOH} = \dfrac{0,1}{1} = 0,1(lít) = 100(ml)$

Na2O+H2O->2NaOH

0,1 0,1 0,2

2NaOH+CuSO4->Na2SO4+Cu(OH)2

0,2 0,1 0,1 0,1

a.mNaOH=0,2.40=8(g)

mdd NaOH=6,2+193,8=200(g)

C%dd NaOH=8/200.100%=4%

b.mCu(OH)2=0,1.98=9,8(g)

c.Cu(OH)2->CuO+H2O

0,1 0,1 0,1

CuO+2HCl->CuCl2+H2O

0,1 0,2

VddHCl=0,2/2=0,1(l)

Câu c mình ko biết làm đúng hay ko

a/

\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)

\(Na_2O+H_2O\rightarrow2NaOH\)

0,15 0,3 (mol)

\(m_{NaOH}=0,3.40=12\left(g\right)\)

\(m_A=90,7+9,3=100\left(g\right)\)

\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)

b/

m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)

\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)

\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)

bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)

pư: 0,3 0,15 0,15 0,15 (mol)

dư: 0 \(\dfrac{23}{380}\) (mol)

\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)

\(m_C=100+200-13,5=286,5\left(g\right)\)

\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)

\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)

\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)

\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)

Na2O+H2O->2NaOH

0,1 0,1 0,2

2NaOH+CuSO4->Na2SO4+Cu(OH)2

0,2 0,1 0,1 0,1

a.mNaOH=0,2.40=8(g)

mdd NaOH=6,2+193,8=200(g)

C%dd NaOH=8/200.100%=4%

b.mCu(OH)2=0,1.98=9,8(g)

c.Cu(OH)2->CuO+H2O

0,1 0,1 0,1

CuO+2HCl->CuCl2+H2O

0,1 0,2

VddHCl=0,2/2=0,1(l)

Na₂O+H₂O→2NaOH

0,1____ 0,1____0,2

2NaOH+CuSO₄->Na₂SO₄+Cu(OH)₂

0,2______ 0,1______ 0,1_____0,1

a.m_NaOH=0,2.40=8(g)

mdd_NaOH=6,2+193,8=200(g)

C%dd_NaOH=\(\dfrac{8}{200}\).100%=4%

b.m\(_{Cu\left(OH\right)_2}\)=0,1.98=9,8(g)

c.Cu(OH)₂→CuO+H₂O

0,1_________ 0,1_0,1

CuO+2HCl→CuCl₂+H₂O

0,1___ 0,2

Vdd_HCl=\(\dfrac{0,2}{2}\)=0,1(l)